We investigated green phosphorescent organic light-emitting diodes (PHOLEDs) with charge control layer (CCL) to produce high efficiency. The CCL and host material which was 4,4,N,N'-dicarbazolebiphenyl (CBP) of bipolar property can control the carrier movement in emitting layer (EML). The performance improvement by the insertion of CCL was realized to the well confined exciton and the reduced triplet exciton quenching effect in EML. Five types of devices (Device A, B, C, D, and E) were fabricated following the thickness of CCL within EML. The properties of device D using optimized thickness of CCL showed external quantum efficiency of 16.22% and luminous efficiency of 55.76 cd/A, respectively.