[표지]
목차
Abstract 7
I. 서론 9
II. 연구내용 및 방법 11
1. 연구내용 11
가. 연구배경 11
나. 연구목표 15
2. 연구 방법 15
가. 대상 폐기물 선정 및 함량 분석 15
나. 기초 성상분석 및 열적처리 조건 도출 18
다. 실험실 규모 열적처리 가능성 평가 19
III. 연구결과 및 고찰 23
1. 국내·외 PCNs 관련 정책 및 규제기준 현황조사 23
가. Polychlorinated naphthalenes 정의 및 특징 23
나. PCNs 발생 및 배출 현황 26
다. 국내·외 PCNs 관련 법적 규제 및 제도 29
2. 대상 시료의 기초분석 및 열적처리 조건 도출 결과 30
가. 대상 폐기물의 PCNs 함량 분석 결과 30
나. 기초분석 및 열적 기초 특성 32
3. 실험실 규모 반응기의 PCNs 함유 폐기물 열적처리 분해 평가 35
가. 열적 처리조건 산정 결과 35
나. 배출가스 분석 결과 36
다. PCNs 최종 분해율 산정 결과 40
4. PCNs 함유 폐기물의 소각처리 관리방안 제시 43
5. 폐기물 소각시설 현장 조사를 통한 PCNs 및 다이옥신 분석 44
IV. 결론 47
참고문헌 49
〈Table 1〉 Designation status of 30 substances in the Stockholm Convention 12
〈Table 2〉 Thermal treatment standards of POPs-containing materials in domestic and foreign countries 14
〈Table 3〉 PCNs-containing target sample groups and selection criteria 16
〈Table 4〉 HRGC/HRMS analysis conditions of PCNs-containing wastes 18
〈Table 5〉 Analysis Conditions for TD and GC/MSD 21
〈Table 6〉 Physical and chemical properties of Polychlorinated naphthalenes 24
〈Table 7〉 Human hazards of PCNs 26
〈Table 9〉 Application status of PCNs by field of use 27
〈Table 10〉 PCNs potential sources and emissions 28
〈Table 11〉 PCNs legal regulations and institutions 29
〈Table 12〉 Results of selected sample PCNs concentration homologue groups 30
〈Table 13〉 Results of Mix Sample in many samples PCNs concentration homologue groups 30
〈Table 14〉 Results of basic analysis of target samples 33
〈Table 15〉 Thermal basis properties of samples in basic experiment 35
〈Table 16〉 Exhaust gas composition after PCNs-containing waste combustion 36
〈Table 17〉 Analysis results of dioxin in exhaust gas and reactor in gas after combustion 39
〈Table 18〉 Allowable dioxin emission standards of incineration facility 40
〈Table 19〉 Results of PCNs concentration and DRE(%) in exhaust gas after incineration 41
〈Table 20〉 Results of PCNs concentration and DRE(%) in exhaust gas and reactor in gas after incineration 42
〈Table 21〉 Treatment conditions of domestic incineration facilities for PCNs containing wastes 43
〈Table 22〉 Results of PCNs concentrations in stack of municipal waste incineration facilities 44
〈Table 23〉 Results of Dioxin concentrations in stack of municipal waste incineration facilities 46
〈Figure 1〉 Designation procedure of new POPs in Stockholm Convention. 13
〈Figure 2〉 Domestic POPs management departments and legal system 14
〈Figure 3〉 Pre-treatment and analysis method processes of PCNs. 17
〈Figure 4〉 Schematic diagram of lab-scale incineration reactor. 20
〈Figure 5〉 PCNs Structural formula 23
〈Figure 6〉 PCDDs/DFs formation pathways by PCNs precursors. 25
〈Figure 7〉 Results of selected sample PCNs concentration homologue groups. 31
〈Figure 8〉 Results of thermogravimetric analysis. 34
〈Figure 9〉 Results of differential thermal analysis. 34
〈Figure 10〉 Analysis results of VOCs concentration in exhaust gas and reactor in gas after PCNs containing waste combustion. 37
〈Figure 11〉 Analysis results of dioxin in exhaust gas and reactor in gas after combustion. 39
〈Figure 12〉 Results of PCNs concentration and DRE(%) in exhaust gas after incineration. 41
〈Figure 13〉 Results of PCNs concentration and DRE(%) in exhaust gas and reactor in gas after incineration 42
〈Figure 14〉 Results of PCNs concentrations in stack of municipal waste incineration facilities. 45