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국문초록 9
Ⅰ. 서론 11
1. 연구 배경 11
2. 연구 목적 12
Ⅱ. 이론 15
1. 상평형 15
1) 상태방정식 방법 15
2) 활동도 계수 방법 16
2. 상평형 모델 19
1) 상태방정식 모델 19
(1) Virial Equation of State 19
(2) van der Waals Equation of State 20
(3) Redlich-Kwong Equation of State 21
(4) SRK(Soave-Redlich-Kwong) Equation 21
(5) PR(Peng-Robinson) Equation 23
2) 활동도 계수 모델 24
(1) Wilson Equation 24
(2) NRTL(Nonrandom Two-Liquid) Equation 25
(3) UNIQUAC(Universal QuasiChemical) Equation 26
Ⅲ. 실험재료 및 실험방법 28
1. 시약 28
2. 실험장치 30
3. 실험방법 34
4. 분석방법 35
Ⅳ. 실험결과 36
1. 활동도 계수 적용 37
1) NMP + Water Binary System 37
2) Water + MMA Binary System 49
2. 상태방정식 적용 60
3. NMP + Water + MMA Ternary System 64
Ⅴ. 결론 68
1) 활동도 계수 방법 68
2) 상태방정식 방법 68
3) 삼성분계 69
4) 추후 과제 69
Ⅵ. Symbols 70
Ⅶ. 참고문헌 72
ABSTRACT 74
Table 1.1 Separation and purification processes of NMP 14
Table 2.1 Recommended cij values for different types of mixtures 26
Table 3.1 Material properties 28
Table 3.2 Constants of Antoine equation 29
Table 3.3 Technical data of the Vapor-Liquid Equilibrium Apparatus Model 602 30
Table 3.4 Experimental conditions of G.C 35
Table 4.1 Experimental vapor-liquid equilibrium data for the binary system NMP(1) + Water(2) at 0.132 bar : liquid-phase mole fraction x1, vapor-phase mole fraction y1, temperature T 38
Table 4.2 Binary interaction parameters for the binary system NMP(1) + Water (2) system at 0.132 bar 48
Table 4.3 Experimental vapor-liquid equilibrium data for the binary system Water(1) + MMA(2) at 1.013 bar : liquid-phase mole fraction x1, vapor-phase mole fraction y1, temperature T 50
Table 4.4 Binary interaction parameters for Water (1) + MMA (2) at 1.013 bar 59
Table 4.5 Parameters for SRK, PR 60
Table 4.6 Interaction parameters of binary system for equation-of-state 63
Table 4.7 Interaction parameters of ternary system for equation-of-state 64
Table 4.8 Experimental vapor-liquid equilibrium data for the ternary system NMP(1) + Water(2) + MMA(3) at 0.132 bar : liquid-phase mole fraction xi, vapor-phase mole fraction yi, temperature T 66
Figure 3.1 Vapor-Liquid Equilibrium Apparatus Model 602, FISCHER 31
Figure 3.2 Diagram of Vapor-Liquid Equilibrium Apparatus 32
Figure 3.3 Control device 33
Figure 4.1 Comparison of experimental results and Wilson model for the binary system NMP(1) + Water(2) at 0.132 bar by CASE Ⅰ 39
Figure 4.2 Comparison of experimental results and Wilson model for the binary system NMP(1) + Water(2) at 0.132 bar by CASE Ⅱ 40
Figure 4.3 Comparison of experimental results and NRTL model for the binary system NMP(1) + Water(2) at 0.132 bar by CASE Ⅰ 41
Figure 4.4 Comparison of experimental results and NRTL model for the binary system NMP(1) + Water(2) at 0.132 bar by CASE Ⅱ 42
Figure 4.5 Comparison of experimental results and UNIQUAC model for the binary system NMP(1) + Water(2) at 0.132 bar by CASE Ⅰ 43
Figure 4.6 Comparison of experimental results and UNIQUAC model for the binary system NMP(1) + Water(2) at 0.132 bar by CASE Ⅱ 44
Figure 4.7 Comparison of experimental results and Wilson, NRTL, UNIQUAC models for the binary system NMP(1) + Water(2) at 0.132 bar by CASE Ⅰ 45
Figure 4.8 Comparison of experimental results and Wilson, NRTL, UNIQUAC models for the binary system NMP(1) + Water(2) at 0.132 bar by CASE Ⅱ 46
Figure 4.9 Comparison of experimental results and Wilson, NRTL, models for the binary system NMP(1) + Water(2) at 1.013 bar 47
Figure 4.10 Comparison of experimental results and Wilson model for the binary system Water(1) +MMA(2) at 1.013 bar by CASE Ⅰ 51
Figure 4.11 Comparison of experimental results and Wilson model for the binary system Water(1) +MMA(2) at 1.013 bar by CASE Ⅱ 52
Figure 4.12 Comparison of experimental results and NRTL model for the binary system Water(1) +MMA(2) at 1.013 bar by CASE Ⅰ 53
Figure 4.13 Comparison of experimental results and NRTL model for the binary system Water(1) +MMA(2) at 1.013 bar by CASE Ⅱ 54
Figure 4.14 Comparison of experimental results and UNIQUAC model for the binary system Water(1) +MMA(2) at 1.013 bar by CASE Ⅰ 55
Figure 4.15 Comparison of experimental results and UNIQUAC model for the binary system Water(1) +MMA(2) at 1.013 bar by CASE Ⅱ 56
Figure 4.16 Comparison of experimental results and WILSON, NRTL, UNIQUAC models for the binary system Water(1) +MMA(2) at 1.013 bar by CASE Ⅰ 57
Figure 4.17 Comparison of experimental results and WILSON, NRTL, UNIQUAC models for the binary system Water(1) +MMA(2) at 1.013 bar by CASE Ⅱ 58
Figure 4.18 Comparison of experimental results and SRK, PR models for the binary system NMP(1) + Water(2) at 0.132 bar 61
Figure 4.19 Comparison of experimental results and SRK, PR models for the binary system Water(1) +MMA(2) at 1.013 bar 62
Figure 4.20 Ternary vapor-liquid equilibrium diagram 67
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