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Title Page 1
초록 4
Abstract 4
Contents 5
Chapter 1. Introduction 9
1.1. Research Background 9
1.1.1. Symmetry in nature 9
1.1.2. Spontaneous symmetry breaking 9
1.2. Research Objective 11
1.3. Bibliography 13
Chapter 2. Periodic arrays of chiral domains generated from the self-assembly of micropatterned achiral lyotropic chromonic liquid crystal 15
2.1. Introduction 15
2.2. Results and discussion 16
2.2.1. Generation of periodic chiral domains using surface anchoring anisotropy 16
2.2.2. Interaction between chiral domains 18
2.2.3. Control of chiral domains with confinement variation 20
2.2.4. Control of chiral domains with chemical additives 21
2.3. Conclusion 21
2.4. Experimental process 22
2.4.1. Sample preparation and characterization 22
2.4.2. Numerical simulation 22
2.5. Bibliography 23
Chapter 3. Fabrication of Arrays of Topological Solitons in Patterned Chiral Liquid Crystals for Real-Time Observation of Morphogenesis 26
3.1. Introduction 26
3.2. Results and discussion 26
3.3. Conclusion 39
3.4. Experimental process 40
3.4.1. Sample preparation and characterization 40
3.4.2. Landau-de Gennes modeling of the chiral liquid crystal 40
3.4.3. Simulation of polarizing optical microscopy images 42
3.4.4. Simulation of time-dependent heat transfer 42
3.4.5. Statistical analysis 42
3.5. Bibliography 42
Chapter 4. Planar spin glass with topologically-protected mazes in the liquid crystal targeting for reconfigurable micro security media 45
4.1. Introduction 45
4.2. Results and discussion 47
4.2.1. Fabrication of the topologically-protected maze 47
4.2.2. Deterministic optical properties of the topologically-protected maze 49
4.2.3. Non-deterministic properties of the topologically-protected maze 51
4.2.4. Reconfiguration of the topologically-protected maze 55
4.2.5. Multi-factor security system with the topologically-protected maze 56
4.3. Conclusion 60
4.4. Experimental process 61
4.4.1. Materials 61
4.4.2. Sample preparation and characterization 61
4.4.3. Digitalization process of CF-3 maze 62
4.4.4. Calculation of PUF statistical value 63
4.4.5. Resolution test 64
4.4.6. Generation of 2D binary random patterns with Monte Carlo simulation of two-dimensional Ising model 64
4.4.7. Fabrication of 2D ferromagnetic and antiferromagnetic patterns with the nematic LCs 65
4.4.8. Numerical simulation of the director fields for topological defects to generate the ferromagnetic pattern 66
4.4.9. Fluorescent dye and reactive mesogen are simultaneously doped Topologically-protected mazes 66
4.5. Bibliography 67
Curriculum Vitae 72
Figure 1.1. Various examples of symmetries found in nature 9
Figure 1.2. Various schematic illustrations and illustration for spontaneous mirror symmetry breaking (SSB). (a)... 10
Figure 1.3. Schematic illustrations for the liquid crystal (LC) phase. Polarized optical microscope images for the... 11
Figure 1.4. SSB phenomena in the LCs. POM images for the (a) uniaxially aligned LC along a red arrow and (b)... 12
Figure 2.1. Substrate patterns and the resulting nematic textures. (a) Schematic illustration of a patterned silicon... 16
Figure 2.2. Chiral domain formation between the air pillars. (a and b) POM images (without and with the λ... 18
Figure 2.3. Symmetry-breaking variation with interpillar spacing. (a-d) The deflection angles of the vertical... 20
Figure 2.4. Control of the racemic domain handedness with the addition of chiral dopants. (a-c) POM images... 21
Figure 3.1. Patterned substrates and enabled highly ordered solitonic structures. (a) Schematic illustrations of... 27
Figure 3.2. Measured cholesteric pitch (p) of the Ch LC versus temperature. The pitch is measured with the... 28
Figure 3.3. Nucleation of torons from topological defects. (a-h) Experimental images of sequential phase... 29
Figure 3.4. Simulation of time-dependent heat transfer. (a, b) Color maps represent one-time point when 5CB is... 30
Figure 3.5. (a-h) Optical microscope images with a polarizer corresponding to Figure 3.3. (i) An out-of-focus... 30
Figure 3.6. Fluorescent confocal microscope (FCM) image of air pillar. (a-c) FCM images of the xy-plane of the... 31
Figure 3.7. Experimental images obtained by POM with a retardation plate of (a) intermediate and (c) stabilized... 31
Figure 3.8. Transformation of cholesteric fingers mediated by topological defects. (a-h) Experimental images of... 33
Figure 3.9. Transformation of CFs. (a-h) Optical microscope images with a polarizer corresponding to Figure... 34
Figure 3.10. POM images of torons and CFs for various lattice spacings. (a-d) Experimental POM images of the... 35
Figure 3.11. Time-dependent thermal gradient according to the spacing (sp) between the air pockets. (a)... 35
Figure 3.12. Transformation of torons and CFs for various d/p and sp. (a-d) POM images with a 530nm... 36
Figure 3.13. A graph for distances between torons according to the spacing (sp) between the air pockets. As sp... 37
Figure 3.14. Computer-simulated images and three-dimensional structures of CF-3s for various sp. As sp... 37
Figure 3.15. Eight distinct types of Ch structures versus d/p and sp between air pockets. In the diagram, the eight... 38
Figure 3.16. Transformation of the Ch structures according to various d/p and sp. (a-c) POM images with a 530... 39
Figure 4.1. Overview of reconfigurable micro security media with the liquid crystals 46
Figure 4.2. POM images of the sequential thermal phase transition of the cholesteric LCs 47
Figure 4.3. A POM image of the topologically-protected maze 48
Figure 4.4. Anisotropic optical property of the cholesteric finger 49
Figure 4.5. Computer simulated refractive indices of topologically-protected maze in the xz-plane 50
Figure 4.6. Non-deterministic properties of the topologically-protected maze 51
Figure 4.7. Flowchart of the digitalization process of the topologically-protected maze using machine learning-... 52
Figure 4.8. inter-HD histograms obtained with 1D binary matrices composed of 16 bits. The 1D binary matrices... 52
Figure 4.9. Evaluation of reliability for detecting the maze according to image resolution 53
Figure 4.10. Schematic illustrations of 2D random patterns with Monte Carlo simulation of the Ising model 54
Figure 4.11. Challenge-response pairs 54
Figure 4.12. Reconfiguration of the topologically-protected maze with the thermal phase transition 55
Figure 4.13. Various elements for additional security primitives that enable a multi-factor security system 57
Figure 4.14. Ferromagnetic patterns with topologically-protected structures 58
Figure 4.15. Antiferromagnetic patterns with topologically-protected structures 58
Figure 4.16. Temperature-dependent fluorescent anisotropy of the topologically-protected mazes when... 59
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