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기사명/저자명
Anion receptor based on cyclic siloxanes substituted with trifluoromethane-sulfonylamide for solid polymer electrolytes / Won Sil Lee ; Seong Ihl Woo ; Dong Wook Kim ; Changjin Lee ; Yongku Kang 인기도
발행사항
Seoul : The Polymer Society of Korea, 2010.03.25
수록지명
Macromolecular research. vol. 18 no. 3 (Mar. 2010), pp.266-270
자료실
[서울관] 정기간행물실(524호)  도서위치안내(서울관)
외부기관 원문
외부기관 원문
제어번호
KINX2010075970
원문

초록보기 더보기

An anion receptor based on cyclic siloxanes substituted with trifluoromethane-sulfonylamide was prepared

to enhance the ionic conductivity of the solid polymer electrolytes. The anion receptor contains four anioncomplexing

sites at its peripherals and bears a geometry with low steric hindrance, which makes the anions access

and bind easily. The anion receptor effectively enhanced the ionic conductivity of the polymer electrolyte containing

LiCl by two orders of magnitude and LiCF3SO3 by one order. The experimental results showed that the anion receptors

trap the anions in a one-to-one coordination between the anion-complexing site and anion. The highest ionic

conductivity was observed at the lowest activation energy, which was estimated from the VTF plot. The anion receptor

was found to be electrochemically stable up to 5 V, which is suitable for a lithium polymer battery.

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참고문헌 (33건) : 자료제공( 네이버학술정보 )더보기

참고문헌 목록에 대한 테이블로 번호, 참고문헌, 국회도서관 소장유무로 구성되어 있습니다.
번호 참고문헌 국회도서관 소장유무
1 Electrical conductivity in ionic complexes of poly(ethylene oxide) 네이버 미소장
2 New electrolytes using Li2O or Li2O2 oxides and tris(pentafluorophenyl) borane as boron based anion receptor for lithium batteries. Vol. 10. pp. 1195 미소장
3 New electrolytes for lithium ion batteries using LiF salt and boron based anion receptors 네이버 미소장
4 Synthesis of a Series of Fluorinated Boronate Compounds and Their Use as Additives in Lithium Battery Electrolytes 네이버 미소장
5 The Synthesis of a New Family of Boron-Based Anion Receptors and the Study of Their Effect on Ion Pair Dissociation and Conductivity of Lithium Salts in Nonaqueous Solutions 네이버 미소장
6 Li^+ Transference Number Enhancement in Polymer Electrolytes by Incorporation of Anion Trapping Boroxine Rings into the Polymer Host 네이버 미소장
7 Novel inorganic–organic polymer electrolytes – preparation and properties 네이버 미소장
8 “Acid-in-chain” versus “base-in-chain” anionic polymer electrolytes for electrochemical devices 네이버 미소장
9 The Synthesis of a New Family of Anion Receptors and the Studies of Their Effect on Ion Pair Dissociation and Conductivity of Lithium Salts in Nonaqueous Solutions 네이버 미소장
10 Synthesis of Anion Receptor Grafted Siloxane Polymers and the Ionic Conductivity Studies of Polymer-Salt Complexes 네이버 미소장
11 Nonaqueous liquid electrolytes for lithium-based rechargeable batteries. 네이버 미소장
12 Fast Ion Transport in Solid. 미소장
13 Effects of Novel Boric Acid Esters on Ion Transport Properties of Lithium Salts in Nonaqueous Electrolyte Solutions and Polymer Electrolytes 네이버 미소장
14 Ion transport in solvent-free polymers 네이버 미소장
15 Polymer Electrolytes: Ionic Transport Mechanisms and Relaxation Coupling 네이버 미소장
16 Li^+ Conductivity of Polysiloxane-Trifluoromethylsulfonamide Polyelectrolytes 네이버 미소장
17 Solid polymer electrolytes based on cross-linked polysiloxane-g-oligo(ethylene oxide): ionic conductivity and electrochemical properties. Vol. 119-121. pp. 448 미소장
18 Photocured PEO-based solid polymer electrolyte and its application to lithium–polymer batteries. Vol. 92. pp. 255 미소장
19 Ion Conduction in Solid Polymer Electrolytes Composed of Graft Copolymer-Lithium Salt 네이버 미소장
20 Proc. Electrochem. Soc.. Vol. 25–99. pp. 534 미소장
21 The Synthesis of a New Family of Boron-Based Anion Receptors and the Study of Their Effect on Ion Pair Dissociation and Conductivity of Lithium Salts in Nonaqueous Solutions 네이버 미소장
22 A Novel Lithium Battery Electrolyte Based on Lithium Fluoride and a Tris(pentafluorophenyl) Borane Anion Receptor in DME 네이버 미소장
23 Solid polymer electrolytes: materials designing and all-solid-state battery applications: an overview 네이버 미소장
24 Comparative Studies of the Electrochemical and Thermal Stability of Two Types of Composite Lithium Battery Electrolytes Using Boron-Based Anion Receptors 네이버 미소장
25 New approaches to the design of polymer and liquid electrolytes for lithium batteries 네이버 미소장
26 Polymer Electrolytes. 미소장
27 Polymer Electrolyte Reviews. pp. 1 미소장
28 Developments of the Advanced All-Solid-State Polymer Electrolyte Lithium Secondary Battery 네이버 미소장
29 Star-Shaped Polymer Electrolyte with Microphase Separation Structure for All-Solid-State Lithium Batteries 네이버 미소장
30 Capacity Fading Mechanism in All Solid-State Lithium Polymer Secondary Batteries Using PEG-Borate/Aluminate Ester as Plasticizer for Polymer Electrolytes 네이버 미소장
31 Effect of thermal history and characterization of plasticized, composite polymer electrolyte based on PEO and tetrapropylammonium iodide salt (Pr 4N +I -) 네이버 미소장
32 Effect of poly(ethylene glycol) dimethyl ether plasticizer on ionic conductivity of cross-linked poly[siloxane-g-oligo(ethylene oxide)] solid polymer electrolytes 소장
33 Preparation and characterization of sulfonated poly(phthalazinone ether sulfone ketone) (SPPESK)/silica hybrid membranes for direct methanol fuel cell applications 소장
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