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1. 일반정보 7
1.1. 물질 정보 7
1.2. 물리화학적 특성 7
1.2 1. 입경 분포 7
1.2.2. 옥탄올-물 분배계수 8
1.2 3. 응집/집적 9
1.2.4. 수용해도 9
1.2 5. 표면전하 9
1.2.6. 다공성 10
1.2.7. 비표면적 10
1.2.8. 표면화학 10
1.2.9. 결정상 11
1.2.10. 기타 물리화학적 특성 정보 11
2. 환경노출 및 환경거동 14
3. 환경 유해성 14
3.1. 수서생물 영향 14
3.1.1. 급성독성 14
3.1.2. 만성독성 16
3.2. 퇴적물 내 생물 영향 16
3.3. 요약 16
4. 인체건강 유해성 17
참고문헌 18
[부록 1] DOSSlER ON DENDRIMERS 20
PREAMBLE 27
FOREWORD 29
ACKNOWLEDGMENTS 31
1. GENERAL INFORMATION 34
1.1. Identification 34
1.2. Composition 34
1.3. Identifiers 34
1.4. Analytical information 34
1.5. Joint submission 34
1.6. Sponsors 34
1.7. Suppliers 34
1.8. Recipients 34
1.9. Product and process oriented research and development 34
2. CLASSIFICATION & LABELLING AND PBT ASSESSMENT 34
2.1. GHS 34
2.2. DSD-DPD 34
3. MANUFACTURE, USE AND EXPOSURE 35
3.1. Technological process 35
3.2. Estimated Quantities 35
3.3. Sites 35
3.4. Information on mixtures 35
3.5. Life Cycle description 35
3.6. Uses advised against 35
3.7. Exposure Scenarios, exposure and risk assessment 35
3.8. Biocidal information 35
3.9. Emissions Information 35
3.10. Application for authorisation of uses 35
4. PHYSICAL AND CHEMICAL PROPERTIES 35
4.1. Appearance/physical state/colour 35
4.2. Melting point/freezing point 35
4.3. Boiling point 35
4.4. Density 35
4.5. Particle size distribution (Granulometry) 36
4.6. Vapour pressure 52
4.7. Partition coefficient 52
4.8. Water solubility 54
4.9. Solubility in organic solvents / fat solubility 56
4.10. Surface tension 56
4.11. Flash point 56
4.12. Auto flammability 56
4.13. Flammability 56
4.14. Explosiveness 56
4.15. Oxidising properties 56
4.16. Oxidation reduction potential 56
4.17. Stability in organic solvents and identity of relevant degradation products 56
4.18. Storage stability and reactivity towards container material 56
4.19. Stability: thermal, sunlight, metals 56
4.20. pH 56
4.21. Dissociation constant 56
4.22. Viscosity 56
4.23. Additional physico-chemical information 56
4.24. Agglomeration/aggregation 61
4.25. Crystalline phase 64
4.26. Crystallite and grain size 66
4.27. Aspect ratio/shape 66
4.28. Specific surface area 66
4.29. Zeta potential 68
4.30. Surface chemistry 72
4.31. Dustiness 75
4.32. Porosity 75
4.33. Pour density 77
4.34. Photocatalytic activity 77
4.35. Radical formation potential 77
4.36. Catalytic activity 77
5. ENVIRONMENTAL FATE AND PATHWAYS 77
6. ECOTOXICOLOGICAL INFORMATION 77
6.1. Aquatic toxicity 77
6.1.1. Short-term toxicity to fish 77
6.1.2. Long-term toxicity to fish 85
6.1.3. Short-term toxicity to aquatic invertebrates 85
6.1.4. Long-term toxicity to aquatic invertebrates 89
6.1.5. Toxicity to aquatic algae and cyanobacteria 89
6.1.6. Toxicity to aquatic plants other than algae 93
6.1.7. Toxicity to microorganisms 93
6.1.8. Toxicity to other aquatic organisms 93
6.2. Sediment toxicity 98
6.3. Terrestrial toxicity 98
6.4. Biological effects monitoring 98
6.5. Biotransformation and kinetics 98
6.6. Additional ecotoxicological information 98
7. TOXICOLOGICAL INFORMATION 103
8. ANALYTICAL METHODS 103
9. RESIDUES IN FOOD AND FEEDINGSTUFFS 107
10. EFFECTIVENESS AGAINST TARGET ORGANISMS 107
11. GUIDANCE ON SAFE USE 107
12. LITERATURE SEARCH 107
13. ASSESSMENT REPORTS 107
14. INFORMATION REQUIREMENTS 107
판권기 108
표 1. 물리화학적 특성 요약 13
그림 1. G3-PAMAM-(NH2)32의 TEM 사진 12
그림 2. G3-PAMAM-(NH2)62의 TEM 사진 12
Table 4.29/1. eta Potential, in mV, G3-and G4-PAMAM-50% C12 dendrimers in H2O or in mixtures H2O/MeOH at different concentrations and time 70
Table 4.30/1. pH measured in water solution of the G3- and G4-PAMAM-(NH2)2(n+2) dendrimers at different concentration 73
Table 4.30/2. pH measured in suspensions of the G3- and G4-PAMAM-50% C12 dendrimers at different concentration and time 74
Table 6.1.8/1. Summary of toxicity dat for G3-PAMAM-(NH2)32 to G4-PAMAM-(NH2)64 in aquatic organisms 97
Table 6.6/1. Cytotoxicity of G3-PAMAM-(NH2)32, G4-PAMAM-(NH2)64, G3-PAMAM-50% C12 G4-PAMAM-50% C12 in H4IIE cells after 24h exposure 101
Table 6.6/2. Cytotoxicity of G3-PAMAM-(NH2)32, G4-PAMAM-(NH2)64, G3-PAMAM-50% C12 G4-PAMAM-50% C12 in H4IIE cells after 72h exposure 101
Table 6.6/3. Cytotoxicity of G3-PAMAM-(NH2)32, G4-PAMAM-(NH2)64, G3-PAMAM-50% C12 G4-PAMAM-50% C12 in RTG-2 cells after 24h exposure 102
Table 6.6/4. Cytotoxicity of G3-PAMAM-(NH2)32, G4-PAMAM-(NH2)64, G3-PAMAM-50% C12 G4-PAMAM-50% C12 in RTG-2 cells after 72h exposure 102
Study by TEM: G3-PAMAM-(NH2)32 59
Figure 1. TEM pictures of G3-PAMAM-(NH2)32 59
Study by TEM: G3-PAMAM-(NH2)62 60
Figure 1. TEM pictures of G3-PAMAM-(NH2)62 60
그래픽목차
Study of Size distributions: G3-PAMAM-(NH2)32 40
Graphic 1. Size distribution of commercial solution 40
Graphic 2. Size distribution during time of solution of 10g/L 41
Graphic 3. Size distributions by Intensity of solution of G3-PAMAM- (NH2)32 41
Graphic 4. Size distributions by Number of solution of G3-PAMAM- (NH2)32 42
Size distributions: G4-PAMAM-(NH2)64 43
Graphic 1. Size distribution of commercial solution 43
Graphic 2. Size distribution during time of solution of 10g/L 44
Graphic 3. Size distributions by Intensity of solution of G4-PAMAM- (NH2)64 44
Graphic 4. Size distributions by Number of solution of G4-PAMAM- (NH2)64 45
Size distributions: G3-PAMAM-50% C12 46
Graphic 1. Size distribution of commercial solution 46
Graphic 2. Size distributions by Intensity of solution of G3-PAMAM-50% C12 46
Graphic 3. Size distributions by Number of solution of G3-PAMAM-50% C12 47
Graphic 4. Size distribution by Intensity of G3-PAMAM-50% C12 47
Size distributions: G4-PAMAM-50% C12 48
Graphic 1. Size distribution of commercial solution 48
Graphic 2. Size distributions by Intensity of solution of G4-PAMAM-50% C12 49
Graphic 3. Size distributions by Number of solution of G4-PAMAM-50% C12 49
Graphic 4. Size distribution by Intensity of G4-PAMAM-50% C12 50
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