Title Page

Contents

Abstract 10

List of abbreviations 12

Part Ⅰ. Organocatalytic regio- and chemoselective reactions 15

Chapter 1. Preparation and Utilization of Contiguous Bisaziridines as Chiral Building Blocks 16

1.1. Introduction 16

1.2. Results and Discussion 35

1.3. Conclusion 56

1.4. Experimental section 57

1.5. Reference 82

Chapter 2. Substrate-Controlled Chemo- and Enantioselective Synthesis of α-Benzylated Enals and Chiral Cyclopropane-Fused 2-Chromanone Derivatives 90

2.1. Introduction 90

2.2. Results and Discussion 101

2.3. Conclusion 128

2.4. Experimental section 130

2.5. References 171

Part Ⅱ. Catalytic C(sp³)-H amination 176

Chapter 3. Catalytic Silyl Halide-promoted C(sp³)-H Amination of Cyclic Benzylic Ethers 177

3.1. Introduction 177

3.2. Results and Discussion 203

3.3. Conclusion 222

3.4. Experimental section 224

3.5. References 239

Part Ⅲ. Preparation of Organic Electrode Materials 255

Chapter 4. Preparation of Organic Electrode Materials based on Nitroxide Radical Polymer for Organic Radical Batteries 256

4.1. Introduction 256

4.2. Results and Discussion 276

4.3. Conclusion 285

4.4. Experimental section 287

4.5. Reference 294

논문요약 301

Appendices 303

Appendix A. (Experimental data in chapter 1) 304

A-1. NMR spectra of compounds 304

A-2. X-ray crystallographic analysis 329

Appendix B. (Experimental data in chapter 2) 341

B-1. NMR spectra of compounds 341

B-2. HPLC spectra of protonation products 394

B-3. X-ray crystallographic analysis (1) 403

B-4. X-ray crystallographic analysis (2) 414

Appendix C. (Experimental data in chapter 3) 425

C-1. NMR spectra of compounds 425