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2-Aminophenol displays a diverse pattern of reactivity in the substitution reaction of α-bromoacetate. The substitution under neutral or basic conditions results in the formation of 1,4-benzoxazinones, whereas Lewis acid-promoted substitution leads to Friedel-Crafts alkylation of 2-aminophenol. Asymmetric synthesis of two regioisomeric 1,4-benzoxazinones is accomplished from the nucleophilic substitution of highly diastereoenriched α-aryl-α-bromoacetates with N-alkyl-2-aminophenols under varied reaction conditions.

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권호기사 목록 테이블로 기사명, 저자명, 페이지, 원문, 기사목차 순으로 되어있습니다.
기사명 저자명 페이지 원문 목차
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Redox-active porous organic polymers for energy storage Chang Wan Kang, Seung Uk Son p. 159-167

Nickel nanoparticles supported on nonreducible mesoporous materials : effects of framework types on the catalytic decomposition of methane Taeho Kim, Bappi Paul, Dong-il Kwon, Sung Chan Nam, Changbum Jo p. 168-171

Monitoring of cell-dependent reduced states using aptamer-functionalized reduction-sensitive quantum dots Gwan-Ho Lee, Sung Muk Kang, Soo Bin Lee, Dohyun Lee, Youngkuk Ko, Jungyeon Nam, Juhyun Jo, Sang Soo Hah p. 172-175

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Naked-eye detection of fluoride ions using a reaction-based colorimetric probe Yun Seon Choi, Namdoo Kim, Kyoung-Jin Jang, Heon-Jin Choi, Seunghan Shin, Se Won Bae p. 176-179

Structure of mono-hydrated aniline dimer cation Mohammad Alauddin, Madhusudan Roy, Sang Hwan Nam, Jae Kyu Song, Seung Min Park p. 188-192

Anion receptors selective for oxoanions of phosphorus and the importance of partial charge Dae Hyup Sohn, Takbum Ohn, Eunbi Han, Amol Balu Atar, Seung Joo Cho, Jongmin Kang p. 193-199

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참고문헌 (22건) : 자료제공( 네이버학술정보 )

참고문헌 목록에 대한 테이블로 번호, 참고문헌, 국회도서관 소장유무로 구성되어 있습니다.
번호 참고문헌 국회도서관 소장유무
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19 In references 4, it has been established that (αS)-products were provided in the substitution of (αR)-1a-c with various nucleophiles via SN2 (like) mechanism. The absolute configuration of 2a, 2b, 2c, 2e, 2g, 2i, 2j and 3a is confirmed to be (S) by comparison of CSP-HPLC retention time with previously reported data (refs. 2h and 6). The absolute configuration of 2d, 2f, 2h and 3b-f is assigned by analogy. 미소장
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