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The corrosion behavior of copper immersed in dilute oxychloride solution (100 μM) was studied through surface investigation and in-situ monitoring of open-circuit potential. The copper corrosion was initiated with copper dissolution into a form of CuCl₂⁻, resulting in mass decrease within the first 40 h of immersion. This was followed by a hydrolysis reaction initiated by the CuCl₂⁻ at the copper surface, after which oxide products were formed and deposited on the surface, resulting in a mass increase. The formation of nucleation sites for copper oxide and its lateral extension during the corrosion process were examined using focused ion beam (FIB)-scanning electron microscopy (SEM). The presence of metastable compounds such as atacamite (CuCl₂⁻$3Cu(OH)₂) on the corroded copper surface was revealed by X-ray photoelectron spectra (XPS) and transmission electron microscopy (TEM)-energy dispersive spectrometry (EDS) analysis.

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권호기사 목록 테이블로 기사명, 저자명, 페이지, 원문, 기사목차 순으로 되어있습니다.
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참고문헌 (29건) : 자료제공( 네이버학술정보 )

참고문헌 목록에 대한 테이블로 번호, 참고문헌, 국회도서관 소장유무로 구성되어 있습니다.
번호 참고문헌 국회도서관 소장유무
1 Copper corrosion in bentonite/saline groundwater solution: Effects of solution and bentonite chemistry 미소장
2 XPS studies of Cu/ZnO/Al2O3 ultra-fine catalysts derived by a novel gel oxalate co-precipitation for methanol synthesis by CO2+H2 미소장
3 Gas phase hydrogenation of maleic anhydride to tetrahydrofuran by Cu/ZnO/TiO2 catalysts in the presence of n-butanol 미소장
4 The oxidation of Cu(I) in electrolyte solutions 미소장
5 Crystallization and electrical resistivity of Cu2O and CuO obtained by thermal oxidation of Cu thin films on SiO2/Si substrates 미소장
6 DEVELOPMENT OF GEOLOGICAL DISPOSAL SYSTEMS FOR SPENT FUELS AND HIGH-LEVEL RADIOACTIVE WASTES IN KOREA 미소장
7 Geochemical Characterization of Rock-Water Interaction in Groundwater at the KURT Site 미소장
8 Corrosion product film formed on the 90/10 copper–nickel tube in natural seawater: Composition/structure and formation mechanism 미소장
9 The measurement and prediction of the corrosion potential of copper in chloride solutions as a function of oxygen concentration and mass-transfer coefficient 미소장
10 Influence of Anions on Corrosion Behavior of Zinc in Tap Water 미소장
11 Corrosion and Galvanic Compatibility Studies of a High-Strength Copper-Nickel Alloy 미소장
12 The preparation and thermodynamic properties of Fe(II)Fe(III) hydroxide-carbonate (green rust 1); Pourbaix diagram of iron in carbonate-containing aqueous media 미소장
13 Electrochemical corrosion of unalloyed copper in chloride media––a critical review 미소장
14 Surface characterization and corrosion behavior of a novel gold-imitation copper alloy with high tarnish resistance in salt spray environment 미소장
15 Tuning the electronic environment of cations and anions using ionic liquid mixtures 미소장
16 Kinetics and Mechanisms of Cu Electrodissolution in Chloride Media 미소장
17 (Reference title not available) 미소장
18 Advanced analysis of copper X‐ray photoelectron spectra 미소장
19 Copper Corrosion and Biocorrosion Events in Premise Plumbing 미소장
20 Direct reaction between silicon and methanol over Cu-based catalysts: investigation of active species and regeneration of CuCl catalyst 미소장
21 Corrosion characteristic of Cu-10Ni-Fex in 3.5 % NaCl 미소장
22 Current Status of the KURT and Long-term In-situ Experiments 미소장
23 Corrosion of copper in alkaline chloride environments 미소장
24 On the origin and chemical evolution of ground water at the Olkiluoto site 미소장
25 Resolving surface chemical states in XPS analysis of first row transition metals, oxides and hydroxides: Sc, Ti, V, Cu and Zn 미소장
26 Corrosion behaviors of SS316L, Ti-Gr.2, Alloy 22 and Cu in KURT groundwater solutions for geological deep disposal 미소장
27 Effect of Chloride Ions on Electrochemical Behavior of Canister Materials 미소장
28 Investigation of Early Corrosion Behavior of Canister Candidate Materials in Oxic Groundwater by the EQCM Method 미소장
29 Designs of Corrosion Modules for Long-Term Corrosion Tests of Canister Materials in Aerobic and Anaerobic Underground Water 미소장