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I. 서론 11

II. 연구사 15

1. NVOC 15

1.1. NVOC의 정의 15

1.2. NVOC의 효능 17

1.3. NVOC 측정항목의 선정 19

III. 재료 및 방법 24

1. 연구대상지 24

1.1. 연구대상지 선정 24

1.2. 연구대상지 입지특성 26

1.3. 연구대상지 식생현황 27

2. NVOC의 측정방법 29

2.1. NVOC의 구성 29

2.2. 포집용 튜브의 선정 30

2.3. NVOC의 분석방법 31

2.4. NVOC의 포집방법 37

3. 물리환경의 측정방법 39

3.1. 계절의 분류 39

3.2. 물리환경의 측정기간 및 방법 41

4. NVOC 농도와 계절별 물리환경의 상관관계 분석방법 43

IV. 결과 및 고찰 44

1. 계절별 NVOC 농도의 측정결과 44

1.1. 겨울철 소나무숲의 NVOC 농도 44

1.2. 봄철 소나무숲의 NVOC 농도 50

1.3. 여름철 소나무숲의 NVOC 농도 56

1.4. 가을철 소나무숲의 NVOC 농도 77

2. 일중 NVOC 농도의 측정결과 83

2.1. 대관령 소나무숲의 24시간 NVOC 특성 83

2.2. 대관령 소나무숲의 24시간 NVOC 농도 추이 84

3. 최대 배출시간에 측정한 NVOC 농도의 측정결과 87

3.1. 대관령 소나무숲의 10분간 NVOC 측정방법 87

3.2. 대관령 소나무숲의 10분간 NVOC 농도의 변화 88

4. 계절별 물리환경의 측정결과 89

4.1. 겨울철 물리환경 측정결과 89

4.2. 봄철 물리환경 측정결과 92

4.3. 여름철 물리환경 측정결과 95

4.4. 가을철 물리환경 측정결과 99

5. NVOC 농도와 계절별 물리환경의 상관관계 102

5.1. 겨울철 NVOC와 숲환경과의 상관관계 결과 102

5.2. 봄철 NVOC와 숲환경과의 상관관계 결과 103

5.3. 여름철 NVOC와 숲환경과의 상관관계 결과 104

5.4. 가을철 NVOC와 숲환경과의 상관관계 결과 105

5.5. 단시간 측정한 NVOC와 숲환경과의 상관관계 결과 106

V. 결론 107

참고문헌 109

ABSTRACT 122

표목차

Table 1. Global VOC Emission Rate Estimates by Source and Class of... 15

Table 2. Literature of NVOC analyte 19

Table 3. BVOC currently included in MEGAN 20

Table 4. NVOC analyte list in korea 21

Table 5. Literature of analyte result(1) 22

Table 6. Literature of analyte result(2) 23

Table 7. The height and DBH of study area 28

Table 8. GC/MS operarting parameters for NVOC 31

Table 9. HS-SPME operarting parameters for NVOC 32

Table 10. Analytical result of LOD-LOQ 34

Table 11. Analytical result of air volume 37

Table 12. Details of Forest environment investigated at the site 41

Table 13. The relationship between altitude and NVOC 76

Table 14. Realationship between NVOC and Forest environment in winter... 102

Table 15. Realationship between NVOC and Forest environment in spring... 103

Table 16. Realationship between NVOC and Forest environment in summer... 104

Table 17. Realationship between NVOC and Forest environment in autumn... 105

Table 18. Realationship between NVOC and Forest environment in the unit... 106

그림목차

Figure 1. The location of study area 25

Figure 2. The study area of view 26

Figure 3. Crown projection of study area(20mX20m) 28

Figure 4. Structures of monoterepenes 29

Figure 5. Stainless Steel Tube 30

Figure 6. Disposable Tube 30

Figure 7. GC/MS for qualitative analysis 32

Figure 8. Calibration curve of the standard material(1) 35

Figure 9. Calibration curve of the standard material(2) 36

Figure 10. Trapping studies of NVOC 38

Figure 11. Forest environment investigated at the site 42

Figure 12. Characteristics of NVOC in Pinus densiflora forest(december) 44

Figure 13. Variation of NVOC in Pinus densiflora forest(december) 45

Figure 14. Characteristics of NVOC in Pinus densiflora forest(january) 46

Figure 15. Variation of NVOC in Pinus densiflora forest(january) 47

Figure 16. Characteristics of NVOC in Pinus densiflora forest(february) 48

Figure 17. Variation of NVOC in Pinus densiflora forest(february) 49

Figure 18. Characteristics of NVOC in Pinus densiflora forest(march) 50

Figure 19. Variation of NVOC in Pinus densiflora forest(march) 51

Figure 20. Characteristics of NVOC in Pinus densiflora forest(april) 52

Figure 21. Variation of NVOC in Pinus densiflora forest(april) 53

Figure 22. Characteristics of NVOC in Pinus densiflora forest(may) 54

Figure 23. Variation of NVOC in Pinus densiflora forest(may) 55

Figure 24. Characteristics of NVOC in Pinus densiflora forest(june) 56

Figure 25. Variation of NVOC in Pinus densiflora forest(june) 57

Figure 26. Characteristics of NVOC in Pinus densiflora forest valley(july-1) 58

Figure 27. Variation of NVOC in Pinus densiflora forest valley(july-1) 59

Figure 28. Characteristics of NVOC in Pinus densiflora forest mountainside(july-1) 60

Figure 29. Variation of NVOC in Pinus densiflora forest mountain side(july-1) 61

Figure 30. Characteristics of NVOC in Pinus densiflora forest mountain top(july-1) 62

Figure 31. Variation of NVOC in Pinus densiflora forest mountaintop(july-1) 63

Figure 32. Characteristics of NVOC in Pinus densiflora forest valley(july-2) 64

Figure 33. Variation of NVOC in Pinus densiflora forest valley(july-2) 65

Figure 34. Characteristics of NVOC in Pinus densiflora forest mountainside(july-2) 66

Figure 35. Variation of NVOC in Pinus densiflora forest mountainside(july-2) 67

Figure 36. Characteristics of NVOC in Pinus densiflora forest mountaintop(july-2) 68

Figure 37. Variation of NVOC in Pinus densiflora forest mountaintop(july-2) 69

Figure 38. Characteristics of NVOC in Pinus densiflora forest valley(august) 70

Figure 39. Variation of NVOC in Pinus densiflora forest valley(august) 71

Figure 40. Characteristics of NVOC in Pinus densiflora forest mountainside(august) 72

Figure 41. Variation of NVOC in Pinus densiflora forest mountainside(august) 73

Figure 42. Characteristics of NVOC in Pinus densiflora forest mountaintop(august) 74

Figure 43. Variation of NVOC in Pinus densiflora forest mountaintop(august) 75

Figure 44. Characteristics of NVOC in Pinus densiflora forest(september) 77

Figure 45. Variation of NVOC in Pinus densiflora forest(september) 78

Figure 46. Characteristics of NVOC in Pinus densiflora forest(october) 79

Figure 47. Variation of NVOC in Pinus densiflora forest(october) 80

Figure 48. Characteristics of NVOC in Pinus densiflora forest(november) 81

Figure 49. Variation of NVOC in Pinus densiflora forest(november) 82

Figure 50. NVOC characteristics of 24 hours in Pinus densiflora forest(july) 83

Figure 51. Progress of NVOC concentration change of 24 hours in Pinus densiflora forest(1) 85

Figure 52. Progress of NVOC concentration change of 24 hours in Pinus densiflora forest(2) 86

Figure 53. Result of Pinus densiflora forest NVOC measurement in the unit of 10 minutes 87

Figure 54. Concentration of Pinus densiflora forest NVOC measurement in the unit of 10 minutes 88

Figure 55. Physical environment of Daegwallyeong Pinus densiflora forest(december) 89

Figure 56. Physical environment of Daegwallyeong Pinus densiflora forest(january) 90

Figure 57. Physical environment of Daegwallyeong Pinus densiflora forest(february) 91

Figure 58. Physical environment of Daegwallyeong Pinus densiflora forest(march) 92

Figure 59. Physical environment of Daegwallyeong Pinus densiflora forest(april) 93

Figure 60. Physical environment of Daegwallyeong Pinus densiflora forest(may) 94

Figure 61. Physical environment of Daegwallyeong Pinus densiflora forest(june) 95

Figure 62. Physical environment of Daegwallyeong Pinus densiflora forest(july-1) 96

Figure 63. Physical environment of Daegwallyeong Pinus densiflora forest(july-2) 97

Figure 64. Physical environment of Daegwallyeong Pinus densiflora forest(august) 98

Figure 65. Physical environment of Daegwallyeong Pinus densiflora forest(september) 99

Figure 66. Physical environment of Daegwallyeong Pinus densiflora forest(october) 100

Figure 67. Physical environment of Daegwallyeong Pinus densiflora forest(november) 101

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