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In this work, nano-sized bismuth (Bi) binding technology has been developed in order to improve the electrochemical characteristics of Bi for detecting heavy metals. A Bi nanopowder synthesized by gas condensation (GC) method exhibits a size smaller than 100 nm. The Bi nanoparticles are uniformly distributed on a carbon surface with strong chemical bonding by using a Nafion solution. The optimum additional amount of Nafion is suggested for dispersion stability and phase stability of the Bi nanoparticles. The detection sensitivity and the detection limit of the nano-Bi fixed electrode are quantitatively estimated from analyses of square wave anodic stripping voltammograms (SWASV). The proposed “mercury-free” carbon strip electrode, modified with a Bi nanopowder, is conveniently to use and is directly applicable to trace metal analysis with neither pre-deposition of Bi nor complicated surface polishing steps.

권호기사

권호기사 목록 테이블로 기사명, 저자명, 페이지, 원문, 기사목차 순으로 되어있습니다.
기사명 저자명 페이지 원문 목차
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참고문헌 목록에 대한 테이블로 번호, 참고문헌, 국회도서관 소장유무로 구성되어 있습니다.
번호 참고문헌 국회도서관 소장유무
1 J. Wang and J. Lu, Electrochem. Commun. 2, 390 (2000). 미소장
2 E. A. Hutton, B. Ogorevc, S. B. Hocevar, F. Weldon, M. R. Smyth and J. Wang, Electrochem. Commun. 3, 707 (2001). 미소장
3 J. Wang, J. Lu, ¨U. A. Kirg¨oz, S. B. Hocevar and B. Ogorevc, Anal. Chim. Acta 434, 29 (2001). 미소장
4 J. Wang, J. Lu, S. B. Hocevar, P. A. M. Farias and B. Ogorevc, Anal. Chem. 72, 3218 (2002). 미소장
5 S. B. Hocevar, J. Wang, R. P. Deo and B. Ogorevc, Electroanal. 14, 112 (2002). 미소장
6 G. Kefala, A. Economou, A. Voulgaropoulos and M. Sofoniou, Talanta 61, 603 (2003). 미소장
7 J. Kruusma, C. E. Banks and R. G. Compton, Anal. Bioanal. Chem. 379, 700 (2004). 미소장
8 L. Lin, N. S. Lawrence, S. Thongngamdee, J. Wang and Y. Lin, Talanta 65, 144 (2005). 미소장
9 L. Lin, S. Thongngamdee, J. Wang, Y. Lin, O. A. Sadik and S. Y. Ly, Anal. Chim. Acta 535, 9 (2005). 미소장
10 R. Pauliukait˙e and C. M. A. Brett, Electroanal. 17, 1354 (2005). 미소장
11 I. Svancara, L. Baldrianova, E. Tesarova, S. B. Hocevar, S. A. A. Elsuccary, A. Economou, S. Sotiropoulos, B. Ogorevc and K. Vytras, Electroanal. 18, 177 (2006). 미소장
12 J. Wang, D. Lu, S. Thongngamdee, Y. Lin and O. A. Sadik, Talanta 69, 914 (2006). 미소장
13 L. Baldrianova, I. Svancara, A. Economou and S. Sotiropoulos, Anal. Chim. Acta 580, 24 (2006). 미소장
14 W. W. Zhu, N. B. Li and H. Q. Luo, Anal. Lett. 39, 2273 (2006). 미소장
15 E. O. Jorge, M. M. M. Neto and M. M. Rocha, Talanta 72, 1392 (2007). 미소장
16 G.-J. Lee, H. M. Lee and C. K. Rhee, Electrochem. Commun. 9, 2514 (2007). 미소장
17 G.-J. Lee, H. M. Lee, Y. R. Uhm, M. K. Lee and C. K. Rhee, Electrochem. Commun. 10, 1920 (2008). 미소장
18 H. M. Lee, G.-J. Lee, H. J. Kim, Y. R. Uhm, M. K. Lee and C. K. Rhee, J. Nanosci. Nanotechnol. 10, 309 (2010). 미소장
19 G.-J. Lee, C. K. Kim, M. K. Lee and C. K. Rhee, Electroanal. 22, 530 (2010). 미소장
20 A. Y. Yermakov, M. A. Uimin, A. A. Mysik, A. Y. Korobeinikov, A. V. Korolyov, N. V. Mushnikov, T. Goto, V. S. Gaviko and N. N. Schegoleva, Mater. Sci. Forum 386-388, 455 (2002). 미소장
21 Y. R. Uhm, W. W. Kim and C. K. Rhee, Phys. Status Solidi A 201, 1934 (2004). 미소장
22 B. S. Han, C. K. Rhee, M. K. Lee and Y. R. Uhm, IEEE Trans. Magn. 42, 3779 (2006). 미소장
23 Y. R. Uhm, B. S. Han, M. K. Lee, S. J. Hong and C. K. Rhee, Mater. Sci. Eng., A 449-457, 813 (2007). 미소장
24 G.-J. Lee, C. K. Kim, M. K. Lee and C. K. Rhee, J. Electrochem. Soc. 157, J241 (2010). 미소장